Product ID:NATIONAL REFRIGERANT II
MSDS Date:06/01/1988
FSC:6830
NIIN:00-281-3036
MSDS Number: BLKXR

NATIONAL REFRIGERANTS, INC

11401 ROOSEVELT BLVD.
PHILADELPHIA, PA 19154
US

Emergency Phone: 609-455-4555/800-424-9300 CHEMTREC

Info Phone: 609-455-4555

Preparer: T. NAPRAVA

Cage: 4J994

NATIONAL REFRIGERANTS INC

BRIDGETON, NJ 08302 US

Telephone: 800-262-0012/215-698-6620

Cage: 4J994

TRICHLOROFLUOROMETHANE (CFC-11) (SARA III)

CAS: 75-69-4

RTECS: PB6125000

OSHA PEL 1000 PPM

ACGIH TLV: C, 1000 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:ORL:>3725MG/KG-RAT;LC50 RAT 26200PPM/4HR
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: VAPOR IS HEAVIER THAN AIR
AND CAN CAUSE SUFFOCATION BY REDUCING OXYGEN AVAILABLE FOR
BREATHING. BREATHING HIGH CONCENTRATIONS OF VAPOR MAY CAUSE
LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF B REATH, & MAY LEAD TO
NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR DEATH. SKIN:
NOT A CORROSIVE OR IRRITANT;
Effects of Overexposure:HOWEVER, REPEATED OR PROLONGED LIQUID CONTACT
CAN CAUSE DEFATTING OF SKIN.
Medical Cond Aggravated by Exposure:SKIN DISEASE: PRODUCT CAN DISSOLVE
THE NATURAL OIL OF THE SKIN, THEREFORE DERMATITIS MAY BE EXPECTED
TO RESULT FROM REPEATED CONTACT. PRE-EXISTING SKIN DISORDERS.

First Aid:INHALATION: REMOVE TO FRESH AIR, CALL PHYSICIAN. IF NOT
BREATHING, GIVE CPR, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. DO NOT GIVE EPINEPHRINE OR SIMILAR DRUGS.
EYE: IN CASE O F CONTACT, IMMEDIATELY FLUSH EYES W/PLENTY OF WATER
FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. SKIN: CLEANSE AFTER USE.

Flash Point Method:TOC
Flash Point:NONE
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS MAY BE
REQUIRED IF DRUMS RUPTURE AND CONTENTS ARE SPILLED UNDER FIRE
CONDITIONS.
Unusual Fire/Explosion Hazard:DRUMS MAY RUPTURE UNDER FIRE CONDITIONS.

Spill Release Procedures:VENTILATE AREA. DO NOT FLUSH INTO SEWERS. DIKE
SPILL. COLLECT ON ABSORBENT MATERIAL & TRANSFER TO STEEL DRUMS FOR
RECOVERY OR DISPOSAL. COMPLY W/FEDERAL, STATE AND LOCAL REGULATIONS
OR REPORTING RELEA SES.

Handling and Storage Precautions:STORE IN A CLEAN, DRY AREA. DO NOT
HEAT ABOVE 125 F.

Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS, NO
RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.
SELF-CONTAINED BREATHING APPARATUS (SCBA) IS REQUIRED IF A SPILL
OCCURS.
Ventilation:NORMAL VENT IS GENERALLY ADEQUATE. USE LOCAL EXHAUST WHEN
LARGE AMTS RELEASED. USE MECHANICAL VENT IN LOW PLACES.
Protective Gloves:BUTYL GLOVES.
Eye Protection:CHEMICAL SPLASH GOGGLES
Supplemental Safety and Health

HCC:G3
Boiling Pt:B.P. Text:75.0F,23.9C
Vapor Pres:.7PSIG@77F
Vapor Density:4.9
pH:NEUTRL
Evaporation Rate & Reference:0.1 (CC14=1)
Solubility in Water:0.1% BY WT @ 77 F
Appearance and Odor:COLORLESS LIQUID; SLIGHT ETHERAL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS - POWDERED AL, ZN, BE, ETC.
Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:HIGH TEMPS (OPEN FLAMES, GLOWING
SURFACES, ETC.) FORMING HYDROCHLORIC & HYDROFLUORIC ACIDS-POSSIBLE
CARBONYL HALIDES.

Waste Disposal Methods:EPA HAZARDOUS WASTE NO. U121; F001; F002. COMPLY
WITH FEDERAL, STATE AND LOCAL REGULATIONS. RECLAIM BY DISTILLATION
OR REMOVE TO A PERMITTED WASTE DISPOSAL FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.